Methanol → Dimethyl 2-formylcyclopropane-1,1-dicarboxylate

HRID 435947

반응식

HRID 435947 반응식
[CH:1]([CH:3]1[CH2:5][C:4]1([C:11]([O:13][CH2:14]C)=[O:12])[C:6]([O:8][CH2:9]C)=[O:7])=[O:2].C(C=C)=O.COC(=O)C(Br)C(OC)=O.CO>C(O)C>[CH:1]([CH:3]1[CH2:5][C:4]1([C:6]([O:8][CH3:9])=[O:7])[C:11]([O:13][CH3:14])=[O:12])=[O:2]

참가 물질

6

반응물 4

HCID 887MethanolHCID 7847AcroleinHCID 70087Dimethyl bromomalonateHCID 5337391,1-Diethyl 2-formylcyclopropane-1,1-dicarboxylate

생성물 1

HCID 10899359Dimethyl 2-formylcyclopropane-1,1-dicarboxylate

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

By following the procedure of D. T. Warner, cited above, used for preparing diethyl 2-formylcyclopropane-1,1-dicarboxylate from acrolein but using equivalent amounts of dimethylbromomalonate and methanol instead of diethylbromomalonate and ethanol, respectively, the title compound, nmr (CDCl3) δ 1.98 (m, 2H), 2.80 (m, 1H), 3.79 (s, 6H), 8.82 (d, J = 4 cps. 1H), is obtained.

출처 및 근거

ORD 기록
ord-316ba71884874509bbaf4ba347aff109
출처 데이터셋
uspto-grants-1977_02
특허 번호
US04007171

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