Performic Acid → 2-(3-Methylsulfinylphenyl)-2,4,5,6-tetrahydro-1,3,4,6,6-pentamethylcyclopenta[c]pyrrole-4-carboxamide

HRID 436326

반응식

HRID 436326 반응식
[CH3:1][S:2][C:3]1[CH:4]=[C:5]([N:9]2[C:13]([CH3:14])=[C:12]3[C:15]([CH3:23])([C:20]([NH2:22])=[O:21])[CH2:16][C:17]([CH3:19])([CH3:18])[C:11]3=[C:10]2[CH3:24])[CH:6]=[CH:7][CH:8]=1.C(OO)=[O:26]>CC(C)=O>[CH3:1][S:2]([C:3]1[CH:4]=[C:5]([N:9]2[C:13]([CH3:14])=[C:12]3[C:15]([CH3:23])([C:20]([NH2:22])=[O:21])[CH2:16][C:17]([CH3:19])([CH3:18])[C:11]3=[C:10]2[CH3:24])[CH:6]=[CH:7][CH:8]=1)=[O:26]

참가 물질

4

반응물 2

HCID 66051Performic AcidHCID 203205762-(3-Methylmercaptophenyl)-2,4,5,6-tetrahydro-1,3,4,6,6-pentamethylcyclopenta[c]pyrrole-4-carboxamide

생성물 1

HCID 234561822-(3-Methylsulfinylphenyl)-2,4,5,6-tetrahydro-1,3,4,6,6-pentamethylcyclopenta[c]pyrrole-4-carboxamide

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

Reaction of the 2-(3-methylmercaptophenyl)-2,4,5,6-tetrahydro-1,3,4,6,6-pentamethylcyclopenta[c]pyrrole-4-carboxamide described above in Example 20CB with one molar equivalent of performic acid in acetone at room temperature affords 2-(3-methylsulfinylphenyl)-2,4,5,6-tetrahydro-1,3,4,6,6-pentamethylcyclopenta[c]pyrrole-4-carboxamide.

출처 및 근거

ORD 기록
ord-109e50caa4d44ecc80b8155b5cd9abd4
출처 데이터셋
uspto-grants-1977_02
특허 번호
US04008250

연결된 노트

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