Tert-Butylhydroquinone → tert-Butyl-1,4-benzoquinone

HRID 436583

반응식

HRID 436583 반응식
[C:1]([C:5]1[CH:11]=[C:10]([OH:12])[CH:9]=[CH:8][C:6]=1[OH:7])([CH3:4])([CH3:3])[CH3:2].S([O-])([O-])(=O)=O.[Na+].[Na+]>[Ag]=O.CCOCC>[C:1]([C:5]1[C:6](=[O:7])[CH:8]=[CH:9][C:10](=[O:12])[CH:11]=1)([CH3:4])([CH3:2])[CH3:3]

참가 물질

5

반응물 2

HCID 16043Tert-ButylhydroquinoneHCID 24436Sodium Sulfate

생성물 1

HCID 19211tert-Butyl-1,4-benzoquinone

시약·촉매·용매 2

HCID 92152Silver(II) oxide촉매HCID 3283Diethyl Ether용매

실험 절차

30 g. of tert-butylhydroquinone (Eastman-Kodak) were dissolved in 200 ml. of anhydrous ether and 30 g. of anhydrous sodium sulfate were added. To this mixture was added 60 g. of silver oxide in small increments. An exothermic reaction ensued. After shaking for 20 minutes, the reaction mixture was filtered and the filtrate evaporated under the hood. Yellow crystals of tert-butyl-p-benzoquinone were obtained melting at 55° -60° C.

후처리

  1. additionTo this mixture was added 60 g
  2. customAn exothermic reaction
  3. filtrationthe reaction mixture was filtered
  4. customthe filtrate evaporated under the hood

출처 및 근거

ORD 기록
ord-d0ceb5f56488462494784dc51387ecbd
출처 데이터셋
uspto-grants-1977_02
특허 번호
US04009200

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