Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hexachlorocyclopentadiene → 6-Tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hexachlorocyclopentadiene | HCID 6478 | — |
| 반응물 | tert-Butyl-1,4-benzoquinone | HCID 19211 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 6-Tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione | HCID 20300626 | — |
반응 단계
Hexachlorocyclopentadiene, 40 g., and 15.4 g. of tert-butyl-p-benzoquinone were dissolved in 300 ml. of toluene and refluxed for four hours. The solution solidified upon cooling to room temperature. The solid was washed with methanol and recrystallized from benzene. Yellow crystals were obtained, melting at 124° -125° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04009200 |
| 출처 데이터셋 | uspto-grants-1977_02 |
| ORD ID | ord-bebd30c4a31c439c8ca2e9df4fd11cbf |
| 출처 메모 | uspto-grants-1977_02 |