Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Diiodomethane → 2-Cyclopropylnaphthalene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Diiodomethane | HCID 6346 | — |
| 반응물 | 2-Vinylnaphthalene | HCID 13230 | — |
| 촉매 | Zinc copper couple | HCID 10290809 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | 2-Cyclopropylnaphthalene | HCID 14668696 | — |
반응 단계
A mixture of 15.5 g. of 2-vinylnaphthalene, 23 g. of diiodomethane, 19.6 g. of zinc-copper couple (comprising 19.5 g. of zinc and 0.1 g. of copper) and 500 ml. of diethyl ether is refluxed for eight hours; the cooled mixture is then filtered, washed with dilute hydrochloric acid, washed with water to neutrality, dried and evaporated to yield 2-cyclopropylnaphthalene.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04009197 |
| 출처 데이터셋 | uspto-grants-1977_02 |
| ORD ID | ord-3501764fa95648adb212bdc65f203d58 |
| 출처 메모 | uspto-grants-1977_02 |