Carbon Dioxide → Isophorone diamine

HRID 436724

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HRID 436724 반응식
[N:1]([CH:4]1[CH2:9][C:8]([CH3:14])([CH2:10][N:11]=C=O)[CH2:7][C:6]([CH3:16])([CH3:15])[CH2:5]1)=C=O.CP1(=O)CCC=C1.CP1(=O)CC=CC1.C(=O)=O.C(O)(=O)C(C)=C>CN(C)C=O>[NH2:1][CH:4]1[CH2:9][C:8]([CH3:14])([CH2:10][NH2:11])[CH2:7][C:6]([CH3:16])([CH3:15])[CH2:5]1

참가 물질

7

반응물 5

HCID 280Carbon DioxideHCID 4093Methacrylic AcidHCID 701042,3-Dihydro-1-methyl-1H-phosphole 1-oxideHCID 702562,5-Dihydro-1-methyl-1H-phosphole 1-oxideHCID 169132Isophorone diisocyanate

생성물 1

HCID 17857Isophorone diamine수율 140%

시약·촉매·용매 1

HCID 6228Dimethylformamide용매3회

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온도
50 °C

실험 절차

After the prepolymer has been cooled to 50° C., 695 parts by weight of dimethyl formamide and 44.4 parts by weight (0.2 mol) of 1-isocyanato-3,3,5-trimethyl-5-isocyanato methyl cyclohexane are added. 34.8 parts by weight (0.2 mol) of a mixture of 2,4- and 2,6-tolylene diisocyanate in a ratio of 8:2, and 2.4 parts by weight (0.02 mol) of a mixture of 1-methyl-1-phospha -2-cyclopenten-1-oxide and 1-methyl-1-phospha -3-cyclopenten-1-oxide, are added to the resulting solution. When the evolution of carbon dioxide has virtually stopped, 17.2 parts by weight (0.2 mol) of methacrylic acid in 17.2 parts by weight of dimethyl formamide are added, followed by stirring at 80° C. until a clear solution is formed. Chain extension with 48 parts by weight (0.28 mol) of 1-amino-3,3,5-trimethyl-5-aminomethyl cyclohexane in 100 parts by weight of dimethyl formamide at 25° C. gives a solution of a polyurethane acyl urea having a viscosity of 1650 cP at 24° C.

후처리

  1. customis formed

출처 및 근거

ORD 기록
ord-d58d548c6fd241158bf5c45fa0106329
출처 데이터셋
uspto-grants-1977_06
특허 번호
US04028310

연결된 노트

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