3-iodo-7-fluoro-5H-dibenzo[a,d]cyclohepten-5-one → 3-iodo-5H-dibenzo[a,d]cyclohepten-5-one

반응식

[I:1][C:2]1[CH:3]=[CH:4][C:5]2[CH:11]=[CH:10][C:9]3[CH:12]=[CH:13][C:14](F)=[CH:15][C:8]=3[C:7](=[O:17])[C:6]=2[CH:18]=1.IC1C=CC2C=CC3C=CC(C)=CC=3C(=O)C=2C=1>>[I:1][C:2]1[CH:3]=[CH:4][C:5]2[CH:11]=[CH:10][C:9]3[CH:12]=[CH:13][CH:14]=[CH:15][C:8]=3[C:7](=[O:17])[C:6]=2[CH:18]=1

참가 물질

반응물 2

HCID 214287393-iodo-7-fluoro-5H-dibenzo[a,d]cyclohepten-5-one

HCID 214287553-iodo-7-methyl-5H-dibenzo[a,d]cyclohepten-5-one

생성물 1

HCID 202322053-iodo-5H-dibenzo[a,d]cyclohepten-5-one

실험 절차

Following the procedure of Step B but substituting for the 3-amino-5H-dibenzo[ a,d]cyclohepten-5-one used therein an equimolecular amount of 3-amino-7-fluoro-5H-dibenzo[a,d]cyclohepten-5-one and 3-amino-7-methyl-5H-dibenzo[a,d]cyclohepten-5-one, there are produced respectively, 3-iodo-7-fluoro-5H-dibenzo[a,d]cyclohepten-5-one and 3-iodo-7-methyl-5H-dibenzo[a,d]cyclohepten-5-one.

출처 및 근거

ORD 기록: ord-5e4ecf219407457a97ce7223e676ccbe
출처 데이터셋: uspto-grants-1977_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04031223

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