3-(5-Benzyloxypentyl)(1-hexenyl)benzene → 5-(3-Hexylphenyl)-pentanol

HRID 439765노트

반응식

HRID 439765 반응식
C([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][C:14]1[CH:15]=[C:16]([CH:20]=[CH:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH:17]=[CH:18][CH:19]=1)C1C=CC=CC=1>CO.[Pd]>[CH2:20]([C:16]1[CH:15]=[C:14]([CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][OH:8])[CH:19]=[CH:18][CH:17]=1)[CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]

참가 물질

4

반응물 1

HCID 539255003-(5-Benzyloxypentyl)(1-hexenyl)benzene

생성물 1

HCID 224078765-(3-Hexylphenyl)-pentanol

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 887Methanol용매

실험 절차

A solution of 840 mgs of 3-(5-benzyloxypentyl)-1-(1-hexenyl)benzene in 25 mls of methanol is hydrogenated over 5% palladium on carbon and then filtered through celite, concentrated, and chromatographed over silica gel (3:2 ether:hexane) to yield pure 5-(3-hexylphenyl)-pentanol.

후처리

  1. filtrationfiltered through celite,
  2. concentrationconcentrated
  3. customchromatographed over silica gel (3:2 ether:hexane)

출처 및 근거

ORD 기록
ord-fd56fa22d76b409eb0ebbbfb54927de7
출처 데이터셋
uspto-grants-1996_05
특허 번호
US05516767

반응 노트

불러오는 중…