((4-(tert-Butyl)phenyl)ethynyl)trimethylsilane → Trimethylsilyl[4-(4-methylpentyl)]phenylethyne

반응식

[CH3:1][Si:2]([C:5]#[C:6][C:7]1[CH:12]=[CH:11][C:10]([C:13]([CH3:16])(C)C)=[CH:9][CH:8]=1)([CH3:4])[CH3:3].[CH3:17][CH:18]([CH3:29])[CH2:19]CCC1C=CC(Br)=CC=1>>[CH3:4][Si:2]([C:5]#[C:6][C:7]1[CH:8]=[CH:9][C:10]([CH2:13][CH2:16][CH2:17][CH:18]([CH3:29])[CH3:19])=[CH:11][CH:12]=1)([CH3:1])[CH3:3]

참가 물질

반응물 2

HCID 14989664((4-(tert-Butyl)phenyl)ethynyl)trimethylsilane

HCID 224090934-(4-Methylpentyl)bromobenzene2회

생성물 1

HCID 54327813Trimethylsilyl[4-(4-methylpentyl)]phenylethyne

실험 절차

Using the same general procedure as described for Compound 21, but using instead 4-(4-methylpentyl)bromobenzene (Compound 30), the title compound was synthesized as a colorless oil. PMR (CDCl3): & 0.32 (9H, s), 0.93 (6H, d, J-6.6 Hz), 1.18-1.29 (2H, m), 1.52-1.70 (3H, m), 2.58 (2H, t, J-7.7 Hz), 7.12 (2H, d, J-8.1 Hz), 7.43 (2H, d, J-8.1 Hz).

출처 및 근거

ORD 기록: ord-6530a09d05024e3ba8c72547979e750b
출처 데이터셋: uspto-grants-1996_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05516904

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