Water → 1-(1-Ethylpropylamino)-4-bromanthraquinone

HRID 441107

반응식

HRID 441107 반응식
[CH2:1]([CH:3]([NH:6][C:7]1[C:20]2[C:19](=[O:21])[C:18]3[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=3)[C:12](=[O:22])[C:11]=2[CH:10]=[CH:9][CH:8]=1)[CH2:4][CH3:5])[CH3:2].O.S([O-])([O-])=O.[Na+].[Na+].[Br:30]Br>C(O)(=O)C>[CH2:1]([CH:3]([NH:6][C:7]1[C:20]2[C:19](=[O:21])[C:18]3[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=3)[C:12](=[O:22])[C:11]=2[C:10]([Br:30])=[CH:9][CH:8]=1)[CH2:4][CH3:5])[CH3:2]

참가 물질

6

반응물 4

HCID 962WaterHCID 24408Bromine3회HCID 24437Sodium SulfiteHCID 229162751-(1-Ethylpropylamino)anthraquinone

생성물 1

HCID 229162741-(1-Ethylpropylamino)-4-bromanthraquinone

시약·촉매·용매 1

HCID 176Acetic Acid용매2회

실험 절차

EPAQ (20.02 g) was dissolved in hot acetic acid. In a separate flask, bromine (12.03 g) was dissolved in acetic acid (ca. 10 mL). The bromine solution was slowly added to the dye solution. The reaction was allowed to proceed for 1/2 hour with occasional shaking The reaction mixture was poured into water (600 mL), and aqueous sodium sulfite was added to discharge the bromine. The aqueous solution was decanted off. The solid was dissolved in methylene chloride, then concentrated, and slowly added to cold methanol, whereupon a solid precipitated.

후처리

  1. additionwas added
  2. customThe aqueous solution was decanted off
  3. dissolutionThe solid was dissolved in methylene chloride
  4. concentrationconcentrated
  5. additionslowly added to cold methanol, whereupon a solid
  6. customprecipitated

출처 및 근거

ORD 기록
ord-c5dd409e8de1488eb2200169ce876e1a
출처 데이터셋
uspto-grants-1996_05
특허 번호
US05521271

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