Butylamine → HCID 135623128, 화합물

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[OH:1][C:2]1[C:3]([C:12](=O)[CH2:13][S:14]([CH3:16])=[O:15])=[CH:4][C:5]2[C:10]([CH:11]=1)=[CH:9][CH:8]=[CH:7][CH:6]=2.[CH2:18]([NH2:22])[CH2:19][CH2:20][CH3:21]>>[CH2:18]([N:22]=[C:12]([C:3]1[C:2]([OH:1])=[CH:11][C:10]2[C:5]([CH:4]=1)=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH2:13][S:14]([CH3:16])=[O:15])[CH2:19][CH2:20][CH3:21]

참가 물질

반응물 2

HCID 8007Butylamine

HCID 127155201-(3-Hydroxynaphthalen-2-yl)-2-(methanesulfinyl)ethan-1-one

생성물 1

HCID 135623128HCID 135623128, 화합물수율 55%

실험 절차

A solution of 3'-hydroxy-2-(methylsulfinyl)-2'-acetonaphthone (10 g, 0.040 mole) in n-butylamine (50 ml) was stirred at room temperature for 24 hrs. The reaction mixture was poured into petroleum ether (400 ml) and the product, which precipitated, was filtered off. Recrystallization from absolute ethanol gave light brown crystals (7.0 g, 55%), mp 162°-164°.

후처리

customthe product, which precipitated
filtrationwas filtered off
customRecrystallization from absolute ethanol

출처 및 근거

ORD 기록: ord-3a91a647ba104c08a13b8c099a781f78
출처 데이터셋: uspto-grants-1977_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04039579

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