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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 441512생성일: 2026년 10월 26일

2-Nitro-2'-hydroxy-3',5'-bis(tert-amyl)azobenzene → 2,4-Di-tert-butyl-6-(5-chloro-2H-benzotriazol-2-yl)phenol

https://huagongshe.com/reaction/441512

반응식

참여 물질

역할이름HCID투입량
반응물2-Nitro-2'-hydroxy-3',5'-bis(tert-amyl)azobenzeneHCID 104111—
반응물2,4-Di-tert-butyl-6-[2-(5-chloro-2-nitrophenyl)hydrazinylidene]cyclohexa-2,4-dien-1-oneHCID 135545180—
생성물2,4-Di-tert-butyl-6-(5-chloro-2H-benzotriazol-2-yl)phenolHCID 7747080.4%

반응 단계

When in Example 1, the 2'-hydroxy-3',5'-di-tert-amyl-2-nitroazobenzene was replaced by an equivalent amount of 2'-hydroxy-3',5'-di-tert-butyl-5-chloro-2-nitroazobenzene, the product 5-chloro-2-(2-hydroxy-3,5-di-tert-butylphenyl)-2H-benzotriazole was obtained after a reaction time of 5 hours in a yield of 80.4% of theory as an isolated product of melting point 151°-154° C. An additional 4.5% yield was present in the mother liquor for an overall yield of 84.9% of theory.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US04041044
출처 데이터셋uspto-grants-1977_08
ORD IDord-a902cf19898e4feeb799c17d21b3124a
출처 메모uspto-grants-1977_08