Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methyl 2-methyl-3-(phenylmethoxy)propanoate → 3-Benzyloxy-2-methylpropan-1-ol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methyl 2-methyl-3-(phenylmethoxy)propanoate | HCID 13531536 | — |
| 반응물 | Sodium bis(2-methoxyethoxy)aluminiumhydride | HCID 21584525 | — |
| 생성물 | 3-Benzyloxy-2-methylpropan-1-ol | HCID 562208 | 90.5% |
반응 단계
Reduction of the rac.-methyl-3-benzyloxy-2-methylpropionate was carried out with sodium bis(2-methoxyethoxy)-aluminum hydride using the procedure described in Example 9. Distillation of the crude product afforded the rac. 3-benzyloxy-2-methyl-1-propanol in 90.5% yield as a colorless liquid, b.p. 94°-98° C. (0.1 mm Hg.).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04041058 |
| 출처 데이터셋 | uspto-grants-1977_08 |
| ORD ID | ord-1ba07ab022f7429c932a7b58e0466687 |
| 출처 메모 | uspto-grants-1977_08 |