Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Phenyl 2-chloro-2-oxoacetate → Carbonochloridic acid, 4-methoxyphenyl ester
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Phenyl 2-chloro-2-oxoacetate | HCID 11423990 | — |
| 반응물 | 4-Methoxyphenyl chloroglyoxylate | HCID 53706464 | — |
| 촉매 | Tetraphenylphosphonium Chloride | HCID 164911 | — |
| 생성물 | Carbonochloridic acid, 4-methoxyphenyl ester | HCID 82128 | — |
반응 단계
The decarbonylation reaction was repeated in the manner as described in Example 70, except that the amount of tetraphenylphosphonium chloride was changed as set forth in Table 11, that the phenyl chloroglyoxylate was replaced with 1.396 mmol. of 4-methoxyphenyl chloroglyoxylate (4-MeO--PCG), and that the reaction temperature and reaction period were changed as set forth in Table 11. The results are also set forth in Table 11.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05892091 |
| 출처 데이터셋 | uspto-grants-1999_04 |
| ORD ID | ord-d83da159e16c4b9983a417cd4ed1f36c |
| 출처 메모 | uspto-grants-1999_04 |