Allylamine → N-allyl-4-nitro-2-trichloromethylphenylsulfenamide

반응식

[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10]Cl)=[C:6]([C:12]([Cl:15])([Cl:14])[Cl:13])[CH:5]=1)([O-:3])=[O:2].[CH2:16]([NH2:19])[CH:17]=[CH2:18]>>[CH2:16]([NH:19][S:10][C:7]1[CH:8]=[CH:9][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][C:6]=1[C:12]([Cl:15])([Cl:14])[Cl:13])[CH:17]=[CH2:18]

참가 물질

반응물 2

HCID 7853Allylamine

HCID 127635554-Nitro-2-trichloromethylbenzenesulfenyl chloride

생성물 1

HCID 23465393N-allyl-4-nitro-2-trichloromethylphenylsulfenamide수율 95%

실험 절차

As in Example 4, 61.4 g of 4-nitro-2-trichloromethylbenzenesulfenyl chloride is reacted with 23 g of allylamine. The hydrochloride is filtered off and the ether phase is concentrated. There is obtained 62 g (95% of theory) of N-allyl-4-nitro-2-trichloromethylphenylsulfenamide as a pale oil.

후처리

filtrationThe hydrochloride is filtered off
concentrationthe ether phase is concentrated

출처 및 근거

ORD 기록: ord-6e3c06f0d8a24476a4061dc20e4e31d1
출처 데이터셋: uspto-grants-1981_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04261924

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