2-Tridecanone oxime → 2-Aminotridecane

HRID 444250노트

반응식

HRID 444250 반응식
[CH3:1][C:2](=[N:14]O)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]>[Pd].C(O)C>[NH2:14][CH:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH3:1]

참가 물질

4

반응물 1

HCID 740543132-Tridecanone oxime

생성물 1

HCID 1232972-Aminotridecane수율 85.6%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 702Ethanol용매

실험 절차

20 g of 2-tridecanone oxime are reduced in 200 ml of abs. ethanol with 2 g of 5% palladium on charcoal, affording 16 g of 2-aminotridecane. Boiling point: 82°-87° C./0.01.

출처 및 근거

ORD 기록
ord-e58b3ba937c7401eae2f4d79ba813ad9
출처 데이터셋
uspto-grants-1981_04
특허 번호
US04263324

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