1-Undecanol → 2-Methylundecanol

HRID 444333

반응식

HRID 444333 반응식
[CH2:1]([OH:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH3:13][O-].[Na+]>CO>[CH3:13][CH:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:1][OH:12]

참가 물질

4

반응물 2

HCID 81841-UndecanolHCID 10942334Sodium Methoxide

생성물 1

HCID 663412-Methylundecanol

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

Another synthesis starts from n-undecanol, which is reacted with methanol in the presence of sodium methylate. 2-methyl-undecanol is formed, which is then dehydrogenated to form the aldehyde. (Chemical Abstracts Vol. 74 [1971], 12552 X.)

출처 및 근거

ORD 기록
ord-7f8fb7dc844e4254b9f7a7be5b8aa604
출처 데이터셋
uspto-grants-1981_04
특허 번호
US04263460

연결된 노트

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