2-Hydroxyethyl acrylate → Urethane acrylate

반응식

OC1C=CC(C(C2C=[CH:15][C:14]([OH:17])=CC=2)(C)C)=CC=1.C1OC1.C1(CN=C=O)C(C[N:28]=[C:29]=[O:30])=CC=CC=1.[C:35]([O:39]CCOC1C=CC=CC=1)(=[O:38])[CH:36]=[CH2:37].C(OCCO)(=O)C=C>>[C:35]([OH:39])(=[O:38])[CH:36]=[CH2:37].[NH2:28][C:29]([O:17][CH2:14][CH3:15])=[O:30]

참가 물질

반응물 4

HCID 131652-Hydroxyethyl acrylate

HCID 39485Phenoxyethyl acrylate

HCID 3035160Bis(isocyanatomethyl)benzene

HCID 22406341Bisphenol-a ethyleneoxide

생성물 1

HCID 21863578Urethane acrylate

실험 절차

To a reactor, 53.3 parts by mass of bisphenol-A/ethyleneoxide 2 mole-adduct, 34.0 parts by mass of xylylene diisocyanate, and 93.5 parts by mass of phenoxyethyl acrylate were added and reacted at 80° C. for 5 hours; then, 6.2 parts by mass of 2-hydroxyethyl acrylate and 0.03 parts by mass of urethanizing catalyst were added and reacted at 80° C. for 5 hours, to obtain a urethane acrylate-based oligomer (i.e. a light curable oligomer).