Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hydrochloric Acid → HCID 86596673, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hydrochloric Acid | HCID 313 | — |
| 반응물 | Isoamyl Nitrite | HCID 8053 | — |
| 반응물 | 5-Tert-butyl-2,3-dihydroinden-1-one | HCID 11030576 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | HCID 86596673 | HCID 86596673 | 137.7% |
반응 단계
5-tert-butyl-indan-1-one (9.39 g, 39 mmol) was dissolved in 150 ml methanol. Isoamyl nitrite (5 g, 43 mmol) and conc. HCl (5 ml) were added, and the reaction stirred at ambient temperature for 44 hours. The solvents were removed under vacuum to give 11.67 grams of crude product which was used without further purification. 1H NMR (300 MHz, CDCl3) 7.82 (d, 1H), 7.51 (s, 1H), 7.49 (d, 1H), 3.83 (s, 2H), 3.50 (s, 1H, OH) 1.34 (s, 9H). MS (CSI) m/e 218 (M+H)+, 235 (m+NH4)+
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08487116B2 |
| 출처 데이터셋 | uspto-grants-2013_07 |
| ORD ID | ord-33f1e9d4c2fa409d9d3d76d67b539f6d |
| 출처 메모 | uspto-grants-2013_07 |