4-Methyl-N-(4-nitrophenyl)benzenamine → N1-(p-Tolyl)benzene-1,4-diamine

HRID 456863노트

반응식

HRID 456863 반응식
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([NH:8][C:9]2[CH:14]=[CH:13][C:12]([N+:15]([O-])=O)=[CH:11][CH:10]=2)=[CH:4][CH:3]=1>C(O)C.[Pd]>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([NH:8][C:9]2[CH:14]=[CH:13][C:12]([NH2:15])=[CH:11][CH:10]=2)=[CH:4][CH:3]=1

참가 물질

4

반응물 1

HCID 948594-Methyl-N-(4-nitrophenyl)benzenamine

생성물 1

HCID 4764072N1-(p-Tolyl)benzene-1,4-diamine수율 85%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 702Ethanol용매

실험 절차

Reduction of the nitro function of N-(4-methylphenyl)-4-nitroaniline (Indian J. Chem. (1981) 20B, 611–613) is carried out in the presence of Pd/C in ethanol, under the conditions described for intermediate 2.2. A grey solid is obtained with a yield of 85%.

후처리

  1. customA grey solid is obtained with a yield of 85%

출처 및 근거

ORD 기록
ord-157ce11635fa45489be0cdd913c77b31
출처 데이터셋
uspto-grants-2007_03
특허 번호
US07186752B2

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