Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triphenylphosphine → (3,4,5-Tribromo-2-thenyl)triphenylphosphonium chloride
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triphenylphosphine | HCID 11776 | — |
| 반응물 | 2,3,4-Tribromo-5-(chloromethyl)thiophene | HCID 15124908 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | (3,4,5-Tribromo-2-thenyl)triphenylphosphonium chloride | HCID 20285678 | — |
반응 단계
Triphenylphosphine (9.0 g.) and 10.4 g. of 3,4,5-tribromo-2-chloromethylthiophene were dissolved in 200 ml. of toluene. The mixture was refluxed overnight under argon, cooled to room temperature and the precipitated phosphonium salt was collected by filtration, washed several times with cold benzene and dried at 80° C. under high vacuum. The resulting (3,4,5-tribromo-2-thenyl)triphenylphosphonium chloride has a m.p. 248°-249° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04061656 |
| 출처 데이터셋 | uspto-grants-1977_12 |
| ORD ID | ord-30186ecb507945b18828e49d02aaa336 |
| 출처 메모 | uspto-grants-1977_12 |