Cerium triacetate → Acetoacetic Acid

HRID 461226

반응식

HRID 461226 반응식
[C:1]([O-:4])(=[O:3])[CH3:2].[Ce+3].[C:6]([O-:9])(=[O:8])[CH3:7].[C:10]([O-])(=[O:12])[CH3:11]>C([O-])(=O)C.[Mn+2].C([O-])(=O)C>[CH3:2][C:1]([O-:4])=[O:3].[CH3:11][C:10]([CH2:7][C:6]([OH:9])=[O:8])=[O:12]

참가 물질

4

반응물 1

HCID 10826Cerium triacetate

생성물 2

HCID 96Acetoacetic AcidHCID 175Acetate

시약·촉매·용매 1

HCID 12525Manganous Acetate촉매

실험 절차

Example 4 was repeated, but replacing the cerium acetate with an equimolar quantity of manganese acetate. After 3 hours there were obtained 0.69 moles of glycol, 0.37 moles of monoacetate and 0.04 moles of diacetate. The percentage of glycol amounted to 63% while the productivity amounted to 32.5 g/h/lt.

출처 및 근거

ORD 기록
ord-e1810f0b82824da585f2b08d86b38a78
출처 데이터셋
uspto-grants-1977_12
특허 번호
US04061868

연결된 노트

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