1,4-Cyclohexanedimethanamine → 1,3-Benzenedimethanamine

반응식

[NH2:1][CH2:2][CH:3]1[CH2:8][CH2:7][CH2:6][CH:5]([CH2:9][NH2:10])[CH2:4]1.NCC1CCC(CN)CC1.NCC1CC2CC1CC2CN.NCC1CC2CC1C(CN)C2>>[C:5]1([CH2:9][NH2:10])[CH:6]=[CH:7][CH:8]=[C:3]([CH2:2][NH2:1])[CH:4]=1

참가 물질

반응물 4

HCID 173541,4-Cyclohexanedimethanamine

HCID 174061,3-Bis(aminomethyl)cyclohexane

HCID 9877437Bicyclo[2.2.1]heptane-2,5-diyldimethanamine

HCID 9920435Bicyclo[2.2.1]heptane-2,6-diyldimethanamine

생성물 1

HCID 151331,3-Benzenedimethanamine

실험 절차

5 to 50 mol % of one or more diamines selected from 1,3-bis-(aminomethyl)-cyclohexane; 1,4-bis-(aminomethyl)-cyclohexane; 2,5-bis-(aminomethyl)-bicyclo-[2,2,1]-heptane; 2,6-bis(aminomethyl)-bicyclo-[2,2,1]-heptane; bis-(4-aminocyclohexyl) derivative of an alkane having from 1 to 6 carbon atoms; and m-xylylenediamine, provided that up to 50 mol % of the m-xylylenediamine may be substituted by p-xylylene diamine,