Ammonia → amaron

HRID 461624노트

반응식

HRID 461624 반응식
[N+:1]([C:4]1([C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:6]([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)O1)([O-])=O.[NH3:19]>>[C:13]1([C:4]2[C:6]([C:7]3[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=3)=[N:19][C:4]([C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=3)=[C:6]([C:7]3[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=3)[N:1]=2)[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1

참가 물질

3

반응물 2

HCID 222AmmoniaHCID 12246834HCID 12246834, 화합물

생성물 1

HCID 275938amaron

실험 절차

12 parts of 2-nitro-2,3-diphenyl-oxirane melting at from 109° to 110° C and 100 parts by volume of liquid ammonia are shaken for 6 hours in an autoclave at 100° and 65 atmospheres. After evaporation of the ammonia, the solid residue is treated with water and the constituent left undissolved is filtered off and recrystallized from glacial acetic acid. 5.2 parts of 2,3,5,6-tetraphenylpyrazine (54% of theory) melting at from 253° to 254° C are obtained.

후처리

  1. customAfter evaporation of the ammonia
  2. additionthe solid residue is treated with water
  3. waitthe constituent left undissolved
  4. filtrationis filtered off
  5. customrecrystallized from glacial acetic acid
  6. custommelting at from 253° to 254° C
  7. customare obtained

출처 및 근거

ORD 기록
ord-baf76a2d4884436388faf5b60b3e5983
출처 데이터셋
uspto-grants-1977_12
특허 번호
US04064124

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