Acenaphthenequinone → 9-Methoxyacenaphtho[1,2-b]quinoxaline

반응식

[CH3:1][O:2][C:3]1[CH:9]=[CH:8][C:6]([NH2:7])=[C:5]([N+:10]([O-])=O)[CH:4]=1.[C:13]1(=O)[C:23]2=[C:24]3[C:19](=[CH:20][CH:21]=[CH:22]2)[CH:18]=[CH:17][CH:16]=[C:15]3[C:14]1=O>>[CH3:1][O:2][C:3]1[CH:4]=[C:5]2[C:6](=[CH:8][CH:9]=1)[N:7]=[C:13]1[C:23]3[CH:22]=[CH:21][CH:20]=[C:19]4[C:24]=3[C:15]([C:14]1=[N:10]2)=[CH:16][CH:17]=[CH:18]4

참가 물질

반응물 2

HCID 6724Acenaphthenequinone

HCID 667934-Methoxy-2-nitroaniline

생성물 1

HCID 6250819-Methoxyacenaphtho[1,2-b]quinoxaline수율 91%

실험 절차

When 0.05 mole each of 4-methoxy-2-nitroaniline and acenaphthenequinone were reacted by the method of Example 1, 12.9 g (91 percent yield) of 9-methoxyacenaphtho[1,2-b]quinoxaline, mp = 194°-195° C. were obtained.

출처 및 근거

ORD 기록: ord-c91b649658454bc59a802ee1dc473d41
출처 데이터셋: uspto-grants-1977_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04064127

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