2,4-Dinitrobenzenesulfenyl chloride → Sulfide, bis(2,4-dinitrophenyl)

HRID 462114

반응식

HRID 462114 반응식
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13]Cl)([O-:3])=[O:2]>C(O)(=O)C>[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13][C:5]1[CH:6]=[CH:7][C:8]([N+:10]([O-:12])=[O:11])=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2])([O-:3])=[O:2]

참가 물질

3

반응물 1

HCID 682512,4-Dinitrobenzenesulfenyl chloride

생성물 1

HCID 95960Sulfide, bis(2,4-dinitrophenyl)

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

To 1.38 g. of 3-butenyltributyltin was added 0.936 g. of 2,4-dinitrobenzene sulfenyl chloride in 20 ml. glacial acetic acid at steam bath temperature. The reaction mixture was warned on the steam bath for 20 minutes, poured into ice water and filtered. The mixture was extracted with pentane, dried and recrystallized from ethanol to yield cyclopropylcarbinyl 2,4-dinitrophenyl sulfide; m.p. 80°-81° C. Analysis for C and H confirmed the composition of the reaction product.

후처리

  1. filtrationfiltered
  2. extractionThe mixture was extracted with pentane
  3. customdried
  4. customrecrystallized from ethanol

출처 및 근거

ORD 기록
ord-b81ce2ccbd9d4e35a163bfaf2c454ca3
출처 데이터셋
uspto-grants-1977_12
특허 번호
US04065480

연결된 노트

불러오는 중…