Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Hydroxide → 3-Bromonaphthalene-1-carboxylic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | 5-Bromobenzo[de]isochromene-1,3-dione | HCID 3907491 | — |
| 촉매 | Mercuric oxide | HCID 30856 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 3-Bromonaphthalene-1-carboxylic acid | HCID 11708609 | — |
반응 단계
To a mixture of 3-bromo-1,8-naphthalic anhydride (compound 74, 22.8 g, 82.4 mmol) and sodium hydroxide (13.2 g, 330 mmol) in water (500 mL) was added a solution of mercury(II) oxide (23.2 g, 107 mmol) in water (70 mL) and glacial acetic acid (24 mL). The reaction mixture was heated at reflux for 4 days and then cooled to room temperature. The resulting solid was filtered and dried in vacuo.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08541380B2 |
| 출처 데이터셋 | uspto-grants-2013_09 |
| ORD ID | ord-389f65625db94b4aa084f756bbdffb05 |
| 출처 메모 | uspto-grants-2013_09 |