Thioanisole → HCID 178506884, 화합물

HRID 462307노트

반응식

HRID 462307 반응식
[C:1]1([S:7][CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C([Li:13])CCC>CCCCCC.O1CCCC1>[C:1]1([S:7][CH2:8][Li:13])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

5

반응물 2

HCID 7520ThioanisoleHCID 178418339Butyllithium

생성물 1

HCID 178506884HCID 178506884, 화합물

시약·촉매·용매 2

HCID 8028Tetrahydrofuran용매2회HCID 8058Hexane용매

실험 절차

To a solution of 1.17 ml. of thioanisole in 20 ml. of dry tetrahydrofuran were added 8.4 ml. of a 1.2M solution of n-butyllithium in n-hexane at -20° C. and the mixture was stirred at the same temperature of 1.5 hours to give a 0.28M solution of phenylthiomethyllithium in tetrahydrofuran.

출처 및 근거

ORD 기록
ord-a2b84e137900498fa3034aa88ad675d5
출처 데이터셋
uspto-grants-1977_12
특허 번호
US04065632

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