Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
P-Cymene → 1,1,3,4,4,6-Hexamethyltetralin
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | P-Cymene | HCID 7463 | — |
| 반응물 | tert-BUTYL CHLORIDE | HCID 10486 | — |
| 반응물 | 3,3-Dimethyl-1-butene | HCID 11210 | — |
| 반응물 | Aluminum(III) Chloride | HCID 6451240 | — |
| 반응물 | Triethylaluminum | HCID 16682930 | — |
| 생성물 | 1,1,3,4,4,6-Hexamethyltetralin | HCID 102750 | — |
반응 단계
p-cymene is reacted with t-butylchloride, neohexene and a mixture of aluminium chloride and triethylaluminium to form 1,1,3,4,4,6-hexamethyl tetralin by the general process described in U.S. Pat. No. 3,856,875 or Japanese 79125647 but modified by cooling the reaction mixture by including dichloromethane in it and refluxing this from the mixture at about 20 mm Hg, thereby maintaining a reaction temperature of about -15° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04515990 |
| 출처 데이터셋 | uspto-grants-1985_05 |
| ORD ID | ord-c6844f2dc1264fd08e3255cb37d2bb8f |
| 출처 메모 | uspto-grants-1985_05 |