2-Naphthol → N-benzyloxycarbonyl glycine beta-naphthyl ester

HRID 46433

반응식

HRID 46433 반응식
[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[OH:11].[NH:12]([C:17]([O:19][CH2:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)=[O:18])[CH2:13][C:14](O)=[O:15]>>[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[O:11][C:14](=[O:15])[CH2:13][NH:12][C:17]([O:19][CH2:20][C:21]1[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=1)=[O:18]

참가 물질

3

반응물 2

HCID 86632-NaphtholHCID 14349Benzyloxycarbonylglycine

생성물 1

HCID 20387046N-benzyloxycarbonyl glycine beta-naphthyl ester수율 72%

실험 절차

β-Naphthol and Z-Gly.OH were treated in the same manner as in Example 78 to obtain N-benzyloxycarbonyl glycine β-naphthyl ester (hereinafter represented by ##STR10## in a yield of 72%.

후처리

  1. additionOH were treated in the same manner as in Example 78

출처 및 근거

ORD 기록
ord-ed09abf9ebd94142bc248139abb05618
출처 데이터셋
uspto-grants-1979_11
특허 번호
US04173563

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