참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Methyl acetoacetate | HCID 7757 | — |
| 반응물 | 2-Methyl-3-buten-2-ol | HCID 8257 | — |
| 반응물 | 6-Methyl-5-hepten-2-one | HCID 9862 | — |
| 반응물 | Aluminum isopropoxide | HCID 11143 | — |
| 생성물 | Isoprene | HCID 6557 | — |
| 생성물 | 2-Methyl-3-buten-2-ol | HCID 8257 | — |
| 생성물 | 6-Methyl-5-hepten-2-one | HCID 9862 | — |
반응 단계
7.5 g of aluminum triisopropylate and 50 g of a reaction product which contains 42 g of 2-methyl-2-hepten-6-one and 5 g of 2-methyl-3-buten-2-ol are heated at 150° C. in the reaction apparatus described in Example 1, and a mixture of 464 g of methyl acetoacetate and 430 g of 2-methyl-3-buten-2-ol is introduced in the course of 18 hours. On working up the mixture by distillation when the reaction has ceased, 490 g of 2-methyl-2-hepten-6-one, 95 g of unconverted 2-methyl-3-buten-2-ol, 13 g of acetone and 4 g of isoprene are obtained. The yield (448 g) is 89% of theory, based on methyl acetoacetate employed, and 90.1%, based on methylbutenol converted.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04173588 |
|---|
| 출처 데이터셋 | uspto-grants-1979_11 |
|---|
| ORD ID | ord-63235544baeb4a01bcd04c12e75ec3ce |
|---|
| 출처 메모 | uspto-grants-1979_11 |
|---|
