Sodium Azide → HCID 13536743, 화합물
반응식
Cl[CH2:2][C:3]([C:5]1[CH:6]=[CH:7][C:8]2[O:12][C:11]([CH3:14])([CH3:13])[S:10][C:9]=2[CH:15]=1)=[O:4].[N-:16]=[N+:17]=[N-:18].[Na+]>C(#N)C>[N:16]([CH2:2][C:3]([C:5]1[CH:6]=[CH:7][C:8]2[O:12][C:11]([CH3:14])([CH3:13])[S:10][C:9]=2[CH:15]=1)=[O:4])=[N+:17]=[N-:18]참가 물질
4
실험 절차
A solution of 20 g of 5-chloroacetyl-2,2-dimethyl-1,3-benzoxathiole (VII) in acetonitrile (100 ml) was stirred for two days with 7 g of finely powdered sodium azide. The reaction mixture was filtered, evaporated and the residue recrystallized from methanol to yield 12 g of 5-azidoacetyl-2,2-dimethyl-1,3-benzoxathiole (VIII), m.p. 52°-53° C.
후처리
- filtrationThe reaction mixture was filtered
- customevaporated
- customthe residue recrystallized from methanol
출처 및 근거
- ORD 기록
- ord-7c2d3559475148de8b9b252d33a9e813
- 출처 데이터셋
- uspto-grants-1985_10
- 특허 번호
- US04548951
반응 노트
불러오는 중…