참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | 3,3'-Dichloroazoxybenzene | HCID 260947 | — |
| 촉매 | Nickel | HCID 935 | — |
| 용매 | Methanol | HCID 887 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 1,2-Bis(3-chlorophenyl)hydrazine | HCID 257919 | 89% |
반응 단계
1.2 g of sodium hydroxide and 0.25 g of Raney nickel are added to a suspension of 53.4 g of 3,3'-dichloroazoxybenzene in 60 ml of methanol and 15 ml of water and the hydrogenation reaction is carried out under a hydrogen pressure of 10 bars. After 90 minutes the mixture is cooled to 10° C. and the product is isolated by filtration. 3,3'-Dichlorohydrazobenzene is obtained in a yield of 89% of theory.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04550207 |
|---|
| 출처 데이터셋 | uspto-grants-1985_10 |
|---|
| ORD ID | ord-92967de8b5334f19bc63a49c9d179edd |
|---|
| 출처 메모 | uspto-grants-1985_10 |
|---|
