Hexachlorocyclopentadiene → 6-Tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione

HRID 46685

반응식

HRID 46685 반응식
[Cl:1][C:2]1([Cl:11])[C:6]([Cl:7])=[C:5]([Cl:8])[C:4]([Cl:9])=[C:3]1[Cl:10].[C:12]([C:16]1[C:17](=[O:23])[CH:18]=[CH:19][C:20](=[O:22])[CH:21]=1)([CH3:15])([CH3:14])[CH3:13]>C1(C)C=CC=CC=1>[C:12]([C:16]1[C:17](=[O:23])[CH:18]2[CH:19]([C:20](=[O:22])[CH:21]=1)[C:3]1([Cl:10])[C:2]([Cl:11])([Cl:1])[C:6]2([Cl:7])[C:5]([Cl:8])=[C:4]1[Cl:9])([CH3:15])([CH3:13])[CH3:14]

참가 물질

4

반응물 2

HCID 6478HexachlorocyclopentadieneHCID 19211tert-Butyl-1,4-benzoquinone

생성물 1

HCID 203006266-Tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

Hexachlorocyclopentadiene, 40 g., and 15.4 g. of tert-butyl-p-benzoquinone were dissolved in 300 ml. of toluene and refluxed for four hours. The solution solidified upon cooling to room temperature. The solid was washed with methanol and recrystallized from benzene. Yellow crystals were obtained melting at 124°-125° C.

후처리

  1. washThe solid was washed with methanol
  2. customrecrystallized from benzene
  3. customYellow crystals were obtained melting at 124°-125° C.

출처 및 근거

ORD 기록
ord-33984a9f0bc7469b92c1d7e96b01d0d9
출처 데이터셋
uspto-grants-1979_11
특허 번호
US04174457

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