Butanethiol → 6-Butylthio-1,2,3,4,9,9-hexachloro-1,4,4a,6,7,8a-hexahydro-1,4-methanonaphthalene-5,8-dione

HRID 46693

반응식

HRID 46693 반응식
[Cl:1][C:2]12[C:14]([Cl:16])([Cl:15])[C:5]([Cl:17])([CH:6]3[CH:11]1[C:10](=[O:12])[CH:9]=[CH:8][C:7]3=[O:13])[C:4]([Cl:18])=[C:3]2[Cl:19].[CH2:20]([SH:24])[CH2:21][CH2:22][CH3:23]>C1C=CC=CC=1>[CH2:20]([S:24][CH:8]1[CH2:9][C:10](=[O:12])[CH:11]2[CH:6]([C:5]3([Cl:17])[C:14]([Cl:15])([Cl:16])[C:2]2([Cl:1])[C:3]([Cl:19])=[C:4]3[Cl:18])[C:7]1=[O:13])[CH2:21][CH2:22][CH3:23]

참가 물질

4

반응물 2

HCID 8012ButanethiolHCID 2289471,2,3,4,9,9-Hexachloro-1,4,4A,8A-tetrahydro-1,4-methanonaphthalene-5,8-dione

생성물 1

HCID 203006186-Butylthio-1,2,3,4,9,9-hexachloro-1,4,4a,6,7,8a-hexahydro-1,4-methanonaphthalene-5,8-dione

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

20 g. of 1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4-methanonaphthalene-5,8-dione, prepared as in Example 1, were dissolved in 60 ml. of benzene and then 10 g. of n-butylmercaptan and a few crystals of ferric chloride were added. This reaction mixture was shaken for 24 hours (Parr shaker). When the benzene was evaporated a white solid was obtained. One recrystallization from benzene-Skelly B mixture yielded white crystals, m.p. 97°-98° C. The infrared spectrum showed strong carbonyl at 1750 cm-1.

후처리

  1. dissolutionwere dissolved in 60 ml
  2. customWhen the benzene was evaporated a white solid
  3. customwas obtained
  4. customOne recrystallization from benzene-Skelly B mixture
  5. customyielded white crystals, m.p. 97°-98° C

출처 및 근거

ORD 기록
ord-ab4b133ffc3e4098bd2f1bbe49c66dce
출처 데이터셋
uspto-grants-1979_11
특허 번호
US04174457

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