Naphthalene → Lithium Naphthalene

HRID 466952노트

반응식

HRID 466952 반응식
[Li:1].[CH:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=[CH:4][CH:3]=1>>[Li:1].[CH:10]1[C:11]2[C:6](=[CH:5][CH:4]=[CH:3][CH:2]=2)[CH:7]=[CH:8][CH:9]=1

참가 물질

3

반응물 2

HCID 931NaphthaleneHCID 3028194Lithium

생성물 1

HCID 57466756Lithium Naphthalene

실험 절차

Lithium shot (1.7 grams) packed in mineral oil (Lithcoa Corporation) was magnetically stirred with naphthalene (15 grams) in dry freshly distilled tetrahydrofuran (50 milliliters) for 16 hours at 25° C. in an argon purged amber sure-seal bottle equipped with a rubber septum. The resultant dark green solution was 2 molar in concentration as determined by titration with 0.1 molar hydrochloric acid and by size exclusion chromatographic analysis of the polymeric products obtained after reaction with multiblock component monomers.

후처리

  1. dry with materialin dry freshly distilled tetrahydrofuran (50 milliliters) for 16 hours at 25° C. in an argon
  2. custompurged
  3. customamber sure-seal bottle
  4. customequipped with a rubber septum
  5. concentrationin concentration
  6. customobtained
  7. customafter reaction with multiblock component monomers

출처 및 근거

ORD 기록
ord-ae22f351c8404af38ac3b298f4ca052e
출처 데이터셋
uspto-grants-1992_10
특허 번호
US05158851

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