Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hexachlorocyclopentadiene → 1,2,3,4,11,11,-Hexachloro-1,4,4a, 9a-tetrahydro-1,4-methanoanthracene-9,10-dione
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hexachlorocyclopentadiene | HCID 6478 | — |
| 반응물 | 1,4-Naphthoquinone | HCID 8530 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 1,2,3,4,11,11,-Hexachloro-1,4,4a, 9a-tetrahydro-1,4-methanoanthracene-9,10-dione | HCID 20386884 | — |
반응 단계
Hexachlorocyclopentadiene (60 g.), 1,4-naphthoquinone (31.6 g.), and 30 ml. of toluene were mixed, heated to reflux temperature, and maintained at this temperature for 4 hours. After cooling to room temperature and extracting the excess hexachlorocyclopentadiene with Skelly "B" solvent, the mixture solidified slowly. This crude brown solid was recrystallized repeatedly from benzene/Skelly "B" mix-solvent (70/30) to yield white crystals, m.p. 116°-118° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04174457 |
| 출처 데이터셋 | uspto-grants-1979_11 |
| ORD ID | ord-cafff56eda074c7088cb899d4fcda43d |
| 출처 메모 | uspto-grants-1979_11 |