N,N-Dimethylaniline → 3-Bromo-2-(prop-2-en-1-yl)phenol

HRID 467077

반응식

HRID 467077 반응식
[Br:1][C:2]1[CH:3]=[C:4]([O:8]CC=C)[CH:5]=[CH:6][CH:7]=1.CN(C)[C:14]1[CH:19]=CC=C[CH:15]=1>>[CH2:19]([C:3]1[C:2]([Br:1])=[CH:7][CH:6]=[CH:5][C:4]=1[OH:8])[CH:14]=[CH2:15]

참가 물질

3

반응물 2

HCID 949N,N-DimethylanilineHCID 257945Allyl m-bromophenyl ether

생성물 1

HCID 153607573-Bromo-2-(prop-2-en-1-yl)phenol

실험 절차

The title compound was synthesized from allyl 3-bromophenyl ether by an ortho Claisen rearrangement in dimethylaniline as described in Helvetica Chemica Acta, 6(1), 14, (1973).

출처 및 근거

ORD 기록
ord-4e9eafa2f0444c939b46757dde75d0e0
출처 데이터셋
uspto-grants-1992_10
특허 번호
US05158956

연결된 노트

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