참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | tert-Butyl hydroperoxide | HCID 6410 | — |
| 반응물 | 1-Octene | HCID 8125 | — |
| 반응물 | Potassium Acetate | HCID 517044 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 생성물 | alpha-Hexyl-gamma-butyrolactone | HCID 86736 | 65% |
반응 단계
A stock solution was prepared by heating at 115° C. 500 milliliters of acetic acid, 150 grams of potassium acetate, and 245 grams of manganous acetate tetrahydrate, Mn(OCOCH3)2.4H2O. A 50-milliliter aliquot of the stock solution was added to 2 milliliters of a 0.312 molar solution of tertiary butyl hydroperoxide in acetic acid. The solution also contained 400 microliters of octene-1. After heating, a hexyl gamma-butyrolactone was obtained with a 65% yield based on the tertiary butyl hydroperoxide.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04175089 |
|---|
| 출처 데이터셋 | uspto-grants-1979_11 |
|---|
| ORD ID | ord-2a15ae7a07b443928874c15f383242ed |
|---|
| 출처 메모 | uspto-grants-1979_11 |
|---|
