Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Piperidine → 2,6-Dimethyl-6-piperidino-4-hepten-2-ol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Piperidine | HCID 8082 | — |
| 반응물 | 2-Methyl-3-buten-2-ol | HCID 8257 | — |
| 반응물 | Triphenylphosphine | HCID 11776 | — |
| 반응물 | 1-Bromo-2-methyl-1-propene | HCID 98560 | — |
| 촉매 | palladium(II) acetate | HCID 167845 | — |
| 생성물 | 2,6-Dimethyl-6-piperidino-4-hepten-2-ol | HCID 54023182 | 31% |
반응 단계
A mixture of 10 mmoles 2-methyl-1-bromo-1-propene, 12.5 mmoles 2-methyl-3-buten-2-ol, 30 mmoles piperidine, 0.20 mmole palladium acetate and 0.40 mmole triphenylphosphine was reacted at 100° C. There was produced 61% of a mixture of nonadienols, 31% 2,6-dimethyl-6-piperidino-4-hepten-2-ol and 6% of what is believed to be 2,6-dimethyl-4-piperidino-5-hepten-2-ol.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04175187 |
| 출처 데이터셋 | uspto-grants-1979_11 |
| ORD ID | ord-2a8da2881cb74fe29c07cbad6f53654a |
| 출처 메모 | uspto-grants-1979_11 |