Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methanethiol → Ethyl 2-[(methylsulfanyl)methyl]prop-2-enoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methanethiol | HCID 878 | — |
| 반응물 | 2-(Bromomethyl)acrylic acid ethyl ester | HCID 310620 | — |
| 반응물 | Sodium | HCID 5360545 | — |
| 용매 | Ethanol | HCID 702 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Ethyl 2-[(methylsulfanyl)methyl]prop-2-enoate | HCID 12463627 | — |
반응 단계
A solution of methylmercaptan (4.8 g.) and sodium (2.3 g.) in absolute ethanol (75 ml.) is added dropwise to a solution of ethyl-2-bromomethylacrylate (19.3 g.) in ethanol (25 ml.). After two hours, it is diluted with water (400 ml.) and extracted with methylene chloride. The organic layer is dried and concentrated to dryness in vacuo to yield ethyl-2-methylthiomethylacrylate.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04176235 |
| 출처 데이터셋 | uspto-grants-1979_11 |
| ORD ID | ord-4a61041afbef48b3896e65e216918e56 |
| 출처 메모 | uspto-grants-1979_11 |