참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Thiophenol | HCID 7969 | — |
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | Dinitrobenzonitrile | HCID 520718 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | 2-Nitro-6-(phenylthio)benzonitrile | HCID 15198241 | — |
반응 단계
To a mixture of 2,6-dinitrobenzonitrile (2.0 g, 10.36 mmol) and K2CO3 (1.43 g, 10.36 mmol) in 5 mL of anhydrous DMF was added PhSH (1.14 ml in 5 mL of DMF) dropwise under nitrogen at 0° C. After the completion of addition, the reaction mixture was stirred at 0° C. for 0.5 hr. Then the reaction mixture was poured into 50 mL of water, the resultant precipitation was collected by filtration, washed with water and dried in the air to give the title product.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US08633186B2 |
|---|
| 출처 데이터셋 | uspto-grants-2014_01 |
|---|
| ORD ID | ord-a274fdeb20124f60921de4318030df38 |
|---|
| 출처 메모 | uspto-grants-2014_01 |
|---|
