2-Cyclopropylethan-1-ol → HCID 67400362, 화합물

HRID 471672

반응식

HRID 471672 반응식
[CH:1]1([CH2:4][CH2:5][OH:6])[CH2:3][CH2:2]1.[N+:7]([C:10]1[CH:17]=[CH:16][CH:15]=[C:14]([N+]([O-])=O)[C:11]=1[C:12]#[N:13])([O-:9])=[O:8]>>[CH:1]1([CH2:4][CH2:5][O:6][C:14]2[CH:15]=[CH:16][CH:17]=[C:10]([N+:7]([O-:9])=[O:8])[C:11]=2[C:12]#[N:13])[CH2:3][CH2:2]1

참가 물질

3

반응물 2

HCID 1376422-Cyclopropylethan-1-olHCID 520718Dinitrobenzonitrile

생성물 1

HCID 67400362HCID 67400362, 화합물수율 85%

실험 절차

Prepared as in Example 187c from 2-cyclopropylethanol and 2,6-dinitrobenzonitrile in 85% yield as a yellow oil. 1H NMR (400 MHz, DMSO-d6) δ 0.15-0.20 (m, 2H), 0.43-0.47 (m, 2H), 0.84-0.89 (m, 1H), 1.69 (q, J=6.8 Hz, 2H), 4.31 (t, J=6.4 Hz, 2H), 7.73-7.76 (m, 1H), 7.86-7.93 (m, 2H). MS 233 (MH+).

출처 및 근거

ORD 기록
ord-1d843aa0780d43f09161a8b67f252945
출처 데이터셋
uspto-grants-2014_01
특허 번호
US08633186B2

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