Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Pyrazine → Decylbenzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Pyrazine | HCID 9261 | — |
| 반응물 | 1-Iododecane | HCID 16314 | — |
| 반응물 | HCID 178418255 | HCID 178418255 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | Decylbenzene | HCID 7716 | 71% |
반응 단계
1-Iododecane (134.1 mg, 0.5 mmol) and a THF solution (0.77 mL, 0.97 M, 0.75 mmol) of phenylmagnesium bromide were used as starting materials, and reacted as in Entry 1. Conditions: The THF solution of phenylmagnesium bromide was added dropwise at 40° C. over 2 hours. 1H-NMR analysis was conducted using pyrazine (29.0 mg, 0.36 mmol) as an internal standard (yield 71%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08637710B2 |
| 출처 데이터셋 | uspto-grants-2014_01 |
| ORD ID | ord-444823a2407942948fa5a1876215c2b5 |
| 출처 메모 | uspto-grants-2014_01 |