13-Oxabicyclo[10.1.0]tridecane → Cyclododecanone

HRID 476780노트

반응식

HRID 476780 반응식
[O:1]1[CH:3]2[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH:2]12.[Cl-].[Li+]>CN1CCCC1=O>[C:2]1(=[O:1])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1

참가 물질

4

반응물 2

HCID 924813-Oxabicyclo[10.1.0]tridecaneHCID 433294Lithium Chloride

생성물 1

HCID 13246Cyclododecanone수율 93.5%

시약·촉매·용매 1

HCID 13387N-methyl-2-pyrrolidone용매

반응 조건

온도
200 °C

실험 절차

A solution containing 25 g of epoxy-cyclododecane, 1 g of lithium chloride, and 20 g of N-methyl-2-pyrrolidone was stirred at 200° C. for 6 hours. The reaction mixture contained 93.5% yield of cyclododecanone.

출처 및 근거

ORD 기록
ord-908967b062ab4a69ab3a755d13761e3b
출처 데이터셋
uspto-grants-1989_12
특허 번호
US04885397

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