P-Cresol → Benzene, 1-(1,1-dimethylethyl)-4-(2-propynyloxy)-

반응식

[CH:1]1[C:6](O)=CC=C(C)[CH:2]=1.[C:9]([C:13]1[CH:18]=[CH:17][C:16]([OH:19])=[CH:15][CH:14]=1)([CH3:12])([CH3:11])[CH3:10]>>[CH2:6]([O:19][C:16]1[CH:15]=[CH:14][C:13]([C:9]([CH3:12])([CH3:10])[CH3:11])=[CH:18][CH:17]=1)[C:1]#[CH:2]

참가 물질

반응물 2

HCID 2879P-Cresol

HCID 73934-tert-Butylphenol

생성물 1

HCID 142674Benzene, 1-(1,1-dimethylethyl)-4-(2-propynyloxy)-수율 98%

실험 절차

Example 14 is repeated except that p-cresol is replaced by 4-t-butylphenol. The product, 4-t-butylphenyl propargyl ether, is isolated as a colorless liquid in 98% yield and characterized by pmr spectroscopy. The product is represented by the following formula: ##STR24##

출처 및 근거

ORD 기록: ord-bdd2ec43859a47e4afb1a2bc73a38d15
출처 데이터셋: uspto-grants-1989_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04885403

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