2-Benzylthio-6,7-dichloro-5-methyl-1,2,4-triazolo[1,5-a]pyrimidine → 2-Benzylthio-6-chloro-5-methyl-1,2,4-triazolo[1,5-a]pyrimidine
반응식
[CH2:1]([S:8][C:9]1[N:20]=[C:12]2[N:13]=[C:14]([CH3:19])[C:15]([Cl:18])=[C:16](Cl)[N:11]2[N:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1>[Cu].[Zn]>[CH2:1]([S:8][C:9]1[N:20]=[C:12]2[N:13]=[C:14]([CH3:19])[C:15]([Cl:18])=[CH:16][N:11]2[N:10]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1참가 물질
3
실험 절차
This material was prepared by reduction of 2-benzylthio-6,7-dichloro-5-methyl-1,2,4-triazolo[1,5-a]pyrimidine with zinc-copper couple following the general procedure described in Example 21. The desired product was isolated in 88% yield as a solid, m.p. 160°-161° C. IR and 1H NMR spectra were in agreement with the assigned structure.
출처 및 근거
- ORD 기록
- ord-192075771a694742932224bdb55d295d
- 출처 데이터셋
- uspto-grants-1989_12
- 특허 번호
- US04886883
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