Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethyl bromoacetate → Ethyl 2-(4-methoxyphenyl)sulfanylacetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethyl bromoacetate | HCID 7748 | — |
| 반응물 | 4-Methoxybenzenethiol | HCID 12765 | — |
| 반응물 | Acetic acid, (phenylthio)-, ethyl ester | HCID 97312 | — |
| 반응물 | Sodium ethoxide | HCID 2723922 | — |
| 생성물 | Ethyl 2-(4-methoxyphenyl)sulfanylacetate | HCID 1482371 | — |
반응 단계
The procedure is as in Example 2 for the preparation of ethyl (phenylthio)acetate starting with ethyl bromoacetate (11.7 g), a 2M ethanolic solution of sodium ethylate (35 cc) and 4-methoxythiophenol (10 g). Ethyl (4-methoxyphenylthio)acetate (13.6 g) is thereby obtained, and is used in the crude state in the subsequent syntheses.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04886835 |
| 출처 데이터셋 | uspto-grants-1989_12 |
| ORD ID | ord-e22bcb3c9cc84b40bb977992fca02a54 |
| 출처 메모 | uspto-grants-1989_12 |