Benzyl mercaptan → Ethyl 2-(Benzylsulfanyl)acetate
반응식
C1(SCC(OCC)=O)C=CC=CC=1.Br[CH2:15][C:16]([O:18][CH2:19][CH3:20])=[O:17].[CH2:21]([SH:28])[C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1>CC[O-].[Na+]>[CH2:21]([S:28][CH2:15][C:16]([O:18][CH2:19][CH3:20])=[O:17])[C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1참가 물질
5
실험 절차
The procedure is as in Example 2 for the preparation of ethyl (phenylthio)acetate starting with ethyl bromoacetate (16.7 g), a 2M ethanolic solution of sodium ethylate (50 cc) and benzylmercaptan (11.7 cc). Ethyl (benzylthio)acetate (19.4 g) is thereby obtained, and is used in the crude state in the subsequent phases.
출처 및 근거
- ORD 기록
- ord-3be483af21e2408cac49ba6efb089264
- 출처 데이터셋
- uspto-grants-1989_12
- 특허 번호
- US04886835
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