Benzyl mercaptan → Ethyl 2-(Benzylsulfanyl)acetate

HRID 477314

반응식

HRID 477314 반응식
C1(SCC(OCC)=O)C=CC=CC=1.Br[CH2:15][C:16]([O:18][CH2:19][CH3:20])=[O:17].[CH2:21]([SH:28])[C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1>CC[O-].[Na+]>[CH2:21]([S:28][CH2:15][C:16]([O:18][CH2:19][CH3:20])=[O:17])[C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1

참가 물질

5

반응물 3

HCID 7509Benzyl mercaptanHCID 7748Ethyl bromoacetateHCID 97312Acetic acid, (phenylthio)-, ethyl ester

생성물 1

HCID 3344750Ethyl 2-(Benzylsulfanyl)acetate

시약·촉매·용매 1

HCID 2723922Sodium ethoxide용매

실험 절차

The procedure is as in Example 2 for the preparation of ethyl (phenylthio)acetate starting with ethyl bromoacetate (16.7 g), a 2M ethanolic solution of sodium ethylate (50 cc) and benzylmercaptan (11.7 cc). Ethyl (benzylthio)acetate (19.4 g) is thereby obtained, and is used in the crude state in the subsequent phases.

출처 및 근거

ORD 기록
ord-3be483af21e2408cac49ba6efb089264
출처 데이터셋
uspto-grants-1989_12
특허 번호
US04886835

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