Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Cyclohexanone, 2-hydroxy- → 3-Methyl-4,6,7,8-tetrahydro-2(3H)-naphthalenone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Cyclohexanone, 2-hydroxy- | HCID 10785 | — |
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 반응물 | 1-Penten-3-one | HCID 15394 | — |
| 반응물 | Lithium diisopropylamide | HCID 2724682 | — |
| 반응물 | 2,3-Dimethyl-2-cyclohexen-1-one | HCID 10887898 | — |
| 용매 | Methanol | HCID 887 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | 3-Methyl-4,6,7,8-tetrahydro-2(3H)-naphthalenone | HCID 10909881 | — |
반응 단계
This material is prepared according to the procedure for Preparation 5 wherein 2-hydroxycyclohexanone is substituted for 2,3-dimethylcyclohexenone, methylbutenone is substituted for MVK, and 2N KOH in MeOH is substituted fro LDA in THF.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04889947 |
| 출처 데이터셋 | uspto-grants-1989_12 |
| ORD ID | ord-ace3d167981649f5b92a1c86044c0fb5 |
| 출처 메모 | uspto-grants-1989_12 |